wpe3B.jpg (2664 bytes)  STAINS & STAIN REMOVAL           

All stone is absorbent, some more so than others. This is due to the stones physical
properties related to its
porosity, permeability and absorption.

ALL STONE IS ABSORBENT

Granite 0.2 - 0.5 Slate 0.1 - 1.7
Marble 0.2 - 0.6 Sandstone 0.2 - 9
Quartzite 0.1 - 1.4 Limestone 0.2 - 12

The staining of stone and masonry surfaces can prove be problematic for a variety
of reasons.

square7.gif (285 bytes)  Some spots that look as if they may be a stain are actually etches or a hazing
      or dulling of a highly polish surface. Marble, limestone and travertine are typical
      stones affected by these situations. These types of situations may also be a
      combination of a etch and a staining substance or a prolonged soiling of the etch
      causing it to appear as a stain.

square7.gif (285 bytes)  The minerals in stone have a definite chemical composition, because of this in some
      situations certain chemical reactions can take place between a part of the chemical
      composition and the staining substance producing a permanent stain to occur.
      Some plant fertilizers can cause permanent chemical reactions to occur.

square7.gif (285 bytes)  Some stones have moisture sensitive minerals and substances that can cause the stone
      to develop stains.
square7.gif (285 bytes)  The ingredients in some stain removal compounds can cause a slight irreversible
      bleaching effect to dark colored marbles and limestone's.

square7.gif (285 bytes)  Using the wrong chemical can carry the stain deeper into the stone or set the stain
      making it permanent.

square7.gif (285 bytes)  Old or deep-seated stains may not be fully removed leaving a slight shadow or they
      may not be removed at all.

square7.gif (285 bytes)  A hazing, dulling or etching of a polished finish may occur.
square7.gif (285 bytes)  The longer a stain remains it migrates deeper into the fabric of the stone and becomes
      more permanent.

 yl_di smal.gif (198 bytes) IDENTIFYING THE STAIN     wpe36.jpg (1346 bytes)
Stains have been classified in a few ways...Organic and inorganic, water-based, oil-based
and have been fitted into five categories...
square7.gif (285 bytes)   Organic : Food, fruits, coffee, tea, beverages, cosmetics and tobacco.
square7.gif (285 bytes)   Oil Base : Greasy foods, cooking oils, grease, tar, skin and hair oils.
square7.gif (285 bytes)   Inks / Dyes : Felt tip markers, pens, natural and synthetic dyes.
square7.gif (285 bytes)   Biological : Vegetation, mold, mildew, algae, fungus, etc.
square7.gif (285 bytes)   Metallic : Iron (rust), copper, bronze, etc.

It is important to try to properly identify the source of the stain for a couple of reasons.
   
square7.gif (285 bytes)  Different types of stains respond to different types of chemical agents and
          removal methods.
   
square7.gif (285 bytes)  If the wrong chemicals and methods are used they may spread the stain, and carry it
          deeper into the stone and permanently set it or create a whole new stain.

Some times the cause of the stain is unknown. If this is the case than ask yourself a few
question and look around to see if the stain fits into one of the five categories, also color
may provide a clue.

COLOR CLUES TO STAIN IDENTIFICATION

STAIN COLOR

POSSIBLE CAUSE

Black

Oil,  grease, tar, asphalt, ink,
shoe polish, mould, moss, fungus,
mildew, animal feces, vegetation, dirt

Brown Shads

Coffee, tea, foods, chocolate,
grease, oil, algae, moss, vegetation
dirt, wood (tannin), tobacco, urine,
animal feces, rust, copper, bronze, dyes, plant fertilizer

Reds Shads

Foods, fruit drinks, blood, ink, dyes, rust, plant fertilizer, dirt

Orange

Foods, fruit drinks, rust, dyes

Green

Algae, mildew, foods, ink, dyes,
copper, bronze

Yellow

Eggs, mustard, oil, grease, urine,
rust

Amber

Varnish, polyurethane

Blue

Plant fertilizer, ink, dyes

Bluish-Greenish

Copper, bronze

Gray

Aluminum, efflorescence, paper

White

Aluminum, efflorescence, plant
fertilizer, paint

Clear

Eggs, shellac, lacquer, varnish,
urethane, polyurethane

Other

Paint, ink, crayon (wax), dyes,
cement coloring stains, pigmented
sealers, colored past waxes, colored grouts

 yl_di smal.gif (198 bytes) STAIN REMOVAL                      wpe37.jpg (1234 bytes)
I
n order to draw out the staining substance that has been absorbed into the stone an
absorbent  material needs to be applied to the stained area. This process is referred to
as a
poultice.

There are several premixed wet poultice products available, as well as powder poultices
that only require the addition of water to activate them. They are
more convenient and
safer to use than formulating your own stain remover. These usually can be purchased
at a marble or tile store. I highly recommend that this type of product be part of your
stain removal kit so that when a staining situation does happen you can address it as soon
as possible.
Make sure that the product you buy is compatible with the stone you
intend to use it on.
Example...Some products will say that it is not to be used on some
types of stones,
read the label thoroughly and do not just take the word of the
salesperson for granted.

Poultices are more effective when plastic is placed over them and taped down. This
prevents the poultice from drying out to quickly, allowing the chemical to work on the
stain. The poultice should remain covered approximately 24 hours, then the plastic
removed. If the poultice is not dry at this time it should be allowed to air dry so the
staining substance can be drawn into the poulticing material. When poultice is dry
remove using a wooden or plastic spatula and rinse well.

The stone may have a dark damp spot where the poultice was, this may take a day or so
to dry in order to determine if the poultice has worked or if another application is needed.
Some stains require a few treatments. A good rule of thumb is...If after two applications
the stain has not changed it may be permanent or it is not responding to chemical and at
this point I would recommend that you call a stone care professional.

It has been estimated that approximately 85% of the stains in stone and masonry materials
can be removed successfully and the remainder will either lighten to one degree or another,
or they are permanent.
                                                                    
wpe37.jpg (1302 bytes)Remove all stains as soon as possible. The longer a stain remains the more difficult it may be to remove.

Do not wipe a wet stain to pick up the solution, this may spread the stain. Use an absorbent
cloth or paper towels to
blot it up.

The following is a general guideline for known stains. If in doubt call a profession stone
care company.

STAIN REMOVAL GUIDE

ORGANIC
STAINS

Mix hydrogen peroxide with a few drops of
ammonia. Pour on the stain and leave until the fizzing stops. Use brush to work in. Rinse with water. If it lightens repeat. If this does not work apply the commercial poultice according to the instruction. More than one application may be necessary.

OIL-BASED
STAINS

Apply poultice. Oil stains usually require a few application to to be removed.

INK / DYE
STAINS

For light colored marble and limestone... add about 1 inch of "DI DI Seven" with enough water to mix with poultice. More than one application may be needed. I have had great success with this method.
For dark marbles...Wipe with Acetone.

BIOLOGICAL
STAINS

Spray with a solution of 3 parts bleach, 1 part water and a few drops of dish detergent. Scrub with a brush unit gone. Rinse thoroughly with clean water.

METALLIC
STAINS

NOTE : DO NOT USE BLEACH!
I recommend using a product call "Iron Out"
Follow the instructions and rinse thoroughly.
It will also remove copper stains as well.

In your Stain Removal Kit you will need some...
                     
square7.gif (285 bytes)   Tape (tan painters tape 2 to 3 in. wide)
                     
square7.gif (285 bytes)   A wooden or plastic spatula
                     
square7.gif (285 bytes)   Plastic (food warp, etc.)
                     
square7.gif (285 bytes)   Hydrogen peroxide 6 to 35%, the higher %
                             can be bought at a beauty supply store.
                     
square7.gif (285 bytes)   Ammonia, bleach
                     
square7.gif (285 bytes)   A product named "DI DI Seven" and "Iron Out",
                             KMart, WalMart and some hardware store sell them.
                     
square7.gif (285 bytes)   Acetone, lacquer thinner these are solvents that can
                             be bought at a hardware stone. They are safe to use
                             on all types of stone.
                     
square7.gif (285 bytes)   A nylon scrub brush and rubber gloves

Stains can be categorized as...very light, light, moderate, severe, and very severe.

Moderate to very severe oil stains in granite and quartzite can prove to be stubborn to
remove using a commercially premixed poultice.

If you have moderate to very severe staining of any kind or you're not quite sure what
caused  the stain it is recommended that before you attempt to remove the stains that
you consult with a qualified stone care professional first.

 yl_di smal.gif (198 bytes) STAIN PROTECTION       wpe39.jpg (3061 bytes)
T
he stone should be treated with a water and or oil repellent. These types of treatments
modify the absorption factor of the stone and minimizes staining.

There are several factors to consider when choosing a sealer for stain protection.

           square7.gif (285 bytes)    The type of stone ( marble, granite, etc.)
           square7.gif (285 bytes)    Its absorption %...
See Stone Types
           square7.gif (285 bytes)    The type of finish...Polished...Honed...Textured
           square7.gif (285 bytes)    The stones location and the possible staining conditions.
                   The Color Clue chart above will give you an idea.
           square7.gif (285 bytes)    Is the product ( sealer ) formulated for a dense stone or
                   for a stone with large pores?
Sealers are not alike in certain respects.
           square7.gif (285 bytes)    What is the service life...6 mos.,1, 2, 5,10 yrs. This is how long the
                   product will work before it needs to be reapplied.
           square7.gif (285 bytes)    Will the product darken the stone?
           square7.gif (285 bytes)    The products and methods used to maintain the stone after it is treated.
                   Some products and methods will shorten the sealers service life.

It is important to understand what a repellent treatment will and will not do.

They will not prevent etching from acidic foods and beverages on marble and limestone.
However, a treated surface will minimize the degree of etching by keeping the offending
substance at the surface not allowing the damaging effects to migrate deeper into the
stone to cause severe etching.
                                                                  
wpe35.jpg (1365 bytes)
A
treated surface is not a total guarantee against staining. Repellent treatments
are not stain-proofers
. If an offending substance is left in contact for a prolonged period
of time a stain may develop, however it will not become deep seated. Therefore, care should
be taken to remove any spills or foods from the surface as soon as possible.

Treating the stone does not make it maintenance free, it still needs to be maintained
with the proper stone care products. Honed and texture surfaces in interior settings will
receive further protection from using a "stone soap". Stone soaps dress the stone leaving a
residue behind which may act as a sealer and a soil releasing agent.

Understanding stone and the products that are available for stone care leads to realistic
expectations and are vital elements for a successful stone maintenance program.

We invite you to contact us with any questions concerning your stone care needs or inquires about Stone Care Internationa Products.

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